1.
Which of the following are representations of the same molecule?(i) CH3CH2CH2CH2CH2CH2(ii) CH3 CH2CH2CH2CH2CH3(iii) CH2CH2CH2 CH3 CH2CH3
Correct Answer
C. Only (ii) and (iii)
Explanation
The correct answer is only (ii) and (iii) because both (ii) and (iii) have the same number and arrangement of atoms. In both representations, there are six carbon atoms in a row, with three hydrogen atoms attached to the first carbon and two hydrogen atoms attached to the last carbon. The only difference between (ii) and (iii) is the position of the three hydrogen atoms in the middle, but this does not affect the overall structure of the molecule. Therefore, (ii) and (iii) are representations of the same molecule.
2.
Which of the following explains why alkanes are called saturated hydrocarbons?
Correct Answer
A. Each carbon contains the maximum possible number of hydrogen atoms.
Explanation
Alkanes are called saturated hydrocarbons because they contain the maximum possible number of hydrogen atoms. In alkanes, all carbon atoms are bonded to four other atoms, either hydrogen or carbon. This results in each carbon atom being saturated with hydrogen atoms, meaning it has the maximum number of hydrogen atoms attached to it. This saturation with hydrogen atoms gives alkanes their stability and low reactivity compared to other organic compounds.
3.
Compounds which contain a carbon-carbon triple bond are classified as which of the following?
Correct Answer
D. Alkynes
Explanation
Compounds that contain a carbon-carbon triple bond are classified as alkynes. Alkynes are a type of hydrocarbon that have a triple bond between two carbon atoms. This triple bond gives alkynes unique properties and reactivity compared to other types of hydrocarbons. Alkenes, on the other hand, have a double bond between two carbon atoms, while alkanes do not have any double or triple bonds. Arenes are a separate class of compounds that contain a benzene ring structure. Therefore, the correct classification for compounds with a carbon-carbon triple bond is alkynes.
4.
In organic compounds a halogen atom can replace which of the following?
Correct Answer
A. Hydrogen
Explanation
In organic compounds, a halogen atom can replace a hydrogen atom. This is because halogens have a similar electron configuration to hydrogen and can easily bond with carbon atoms to form stable organic compounds. Halogen substitution reactions are common in organic chemistry and are used to introduce halogen atoms into organic molecules.
5.
Which of the following is a gas at room temperature and pressure?
Correct Answer
C. Butane
Explanation
Butane is a gas at room temperature and pressure. It has a boiling point of -1°C and a melting point of -138.3°C, which means it exists as a gas at typical room temperature and pressure conditions. Hexane and pentane are both liquids at room temperature and pressure, while "none of them" is incorrect as butane fits the criteria.
6.
What is the IUPAC name of:
CH2CH2CH2CH3
CH3CCH2CH3
CH2CH2CH3
Correct Answer
C. 2-butyl-3-propyl-butane
Explanation
"2-butyl-3-propyl-butane" is a systematic name given to a compound with a main chain of four carbon atoms (butane). It has a butyl group (a four-carbon chain) attached to the second carbon atom and a propyl group (a three-carbon chain) attached to the third carbon atom of the main chain. This naming convention precisely describes the structure of the molecule, indicating the positions and types of the substituent groups.
7.
Which of the following is true when there is a single substituent on cyclohexane?
Correct Answer
D. The substituent will prefer to be in the equatorial position
Explanation
When there is a single substituent on cyclohexane, the substituent will prefer to be in the equatorial position. This is because the axial position is less stable due to steric hindrance. Placing the substituent in the equatorial position allows for greater separation between the substituent and the other groups attached to the cyclohexane ring, reducing steric interactions and increasing stability. Therefore, the substituent will favor the equatorial position over the axial position.
8.
How many moles of oxygen are consumed by the complete combustion of one mole of propane, C3H8?
Correct Answer
C. 5
Explanation
The complete combustion of propane, C3H8, produces carbon dioxide (CO2) and water (H2O). The balanced chemical equation for this reaction is: C3H8 + 5O2 -> 3CO2 + 4H2O. From the equation, we can see that for every mole of propane consumed, 5 moles of oxygen are required. Therefore, the correct answer is 5.
9.
Which of the following has the highest boiling point?
Correct Answer
C. Nonane
Explanation
Nonane has the highest boiling point among the given options. Boiling point is determined by the strength of intermolecular forces between molecules. Nonane has a larger number of carbon atoms compared to hexane, octane, and heptane, which results in stronger London dispersion forces. These forces require more energy to break, leading to a higher boiling point for nonane.
10.
In which of the following classes of organic compounds is an oxygen atom bonded to a hydrogen atom?
Correct Answer
A. Alcohols
Explanation
Alcohols are a class of organic compounds where an oxygen atom is bonded to a hydrogen atom. This is because alcohols have a hydroxyl group (-OH) attached to a carbon atom. Aldehydes, on the other hand, have a carbonyl group (-CHO) instead of a hydroxyl group. Amines do not have any oxygen-hydrogen bonds, as they are compounds where a nitrogen atom is bonded to one or more carbon atoms. Therefore, the correct answer is alcohols.
11.
Which of the following is a constitutional isomer of butane, CH3(CH2)2CH3 ?
Correct Answer
A. CH3CHCH3
CH3
Explanation
A constitutional isomer is a compound that has the same molecular formula but a different arrangement of atoms. In this case, the given compound is butane (CH3(CH2)2CH3), which has four carbon atoms in a straight chain. The isomer CH3CHCH3, also known as 2-methylpropane or isobutane, has the same molecular formula but a different arrangement of atoms. It has a branched structure with a methyl group attached to the second carbon atom. Therefore, it is a constitutional isomer of butane.
12.
In which of the following types of reactions is sulfuric acid used as a catalyst?
Correct Answer
A. Hydration
Explanation
Sulfuric acid is used as a catalyst in the hydration reaction. In this type of reaction, water molecules are added to a compound, resulting in the formation of a new compound. Sulfuric acid helps to facilitate this reaction by providing a suitable environment for the reaction to occur, increasing the reaction rate without being consumed in the process.
13.
When listing the substituents in correct order, which of the following should not be ignored?
Correct Answer
A. Iso
Explanation
When listing the substituents in correct order, the prefix "iso" should not be ignored. The prefix "iso" is used to indicate that the substituent is attached to a branch point in the carbon chain. It is important to include this prefix in the correct order to accurately describe the molecule's structure.
14.
Which of the following chemicals, when pure, will have different properties if it is synthesized in the laboratory than if it is obtained from a natural source?
Correct Answer
D. None of these
Explanation
The correct answer is "none of these" because all of the listed chemicals, ethanol, vitamin C, and taxol, will have the same properties regardless of whether they are synthesized in a laboratory or obtained from a natural source. The properties of a chemical compound are determined by its molecular structure, which remains the same regardless of its origin. Therefore, there would be no difference in the properties of these chemicals based on their source.
15.
Which isomer of pentane has the lowest boiling point?
Correct Answer
A. 2,2-dimethypropane
Explanation
2,2-dimethylpropane has the lowest boiling point among the given isomers of pentane. This is because 2,2-dimethylpropane is a branched isomer, which means it has a lower surface area compared to the other isomers. The boiling point of a compound is determined by the strength of intermolecular forces, such as van der Waals forces. Branched isomers have fewer points of contact between molecules, resulting in weaker intermolecular forces and a lower boiling point. Therefore, 2,2-dimethylpropane has the lowest boiling point among the given isomers of pentane.
16.
Compounds which contain a carbon-carbon double bond are classified as which of the following?
Correct Answer
D. Alkenes
Explanation
Compounds that contain a carbon-carbon double bond are classified as alkenes. Alkenes are unsaturated hydrocarbons that have at least one double bond between two carbon atoms. This double bond gives alkenes their characteristic reactivity and makes them different from alkanes, which only have single bonds between carbon atoms. Alkynes have triple bonds, while arenes are compounds that contain a benzene ring. Therefore, the correct classification for compounds with a carbon-carbon double bond is alkenes.
17.
Alkanes belong to which class of hydrocarbons?
Correct Answer
C. Saturated
Explanation
Alkanes belong to the class of hydrocarbons known as saturated. This is because alkanes contain only single bonds between carbon atoms, resulting in a maximum number of hydrogen atoms bonded to each carbon atom. This arrangement of single bonds and maximum hydrogen atoms makes alkanes saturated with hydrogen, hence the classification.
18.
What is the IUPAC name of:
CH3CH(CH3)CH2CH2CH2CH2CH2CH2CH2CH2CH2CH3
Correct Answer
C. 1-isopropyl-1-propylcyclohexane
Explanation
The IUPAC name of the given compound is 1-isopropyl-1-propylcyclohexane. This is because the compound contains a cyclohexane ring with two substituents attached to it. The first substituent is an isopropyl group (CH3CH(CH3)CH2-) attached to the first carbon of the ring, and the second substituent is a propyl group (CH3CH2CH2-) attached to the first carbon of the ring as well. Therefore, the correct IUPAC name is 1-isopropyl-1-propylcyclohexane.
19.
Which of the following is the most characteristic reaction of alkenes?
Correct Answer
A. Addition
Explanation
The most characteristic reaction of alkenes is addition. Alkenes have a double bond between carbon atoms, which makes them highly reactive. Addition reactions involve breaking the double bond and adding new atoms or groups to the carbon atoms. This can result in the formation of new compounds with different properties. Oxidation, reduction, and substitution reactions can also occur with alkenes, but addition reactions are the most common and distinctive.
20.
In organic compounds which of the following elements normally forms three covalent bonds?
Correct Answer
B. Nitrogen
Explanation
Nitrogen is the element that normally forms three covalent bonds in organic compounds. This is because nitrogen has five valence electrons and needs three more to complete its octet. By forming three covalent bonds, nitrogen can achieve a stable electron configuration. Hydrogen can only form one covalent bond, carbon can form four covalent bonds, and oxygen can form two covalent bonds. Therefore, nitrogen is the only element among the options that can form three covalent bonds.